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Beilstein J. Org. Chem. 2014, 10, 1651–1656, doi:10.3762/bjoc.10.172
Graphical Abstract
Figure 1: Possible 1,6-anydro derivatives for D-galactose.
Scheme 1: Reported synthesis of 1,6-anhydro-α-D-galactofuranose [16,17].
Figure 2: Examples of glycobiological tools synthesized from compound 5 [29-31].
Scheme 2: D-Galactofuranosylation by the glycosyl iodide method [32-35].
Scheme 3: Synthesis of 1,6-anhydro-α-D-galactofuranose from per-O-tert-butyldimethylsilyl-D-Galf.
Figure 3: Furanosic derivatives with free primary hydroxy group.